Liste der Veröffentlichungen
Leider wurde diese Liste seit 2003 nicht aktualisiert, wir arbeiten daran
Publikationen
1.) Gutmann S., Burger P., Prosenc M. H. und Brintzinger H. H. (1990): Ansa-metallocene derivatives 20. An assignment of H-1-NMR and C-13-NMR signals in ansa-Metallocene complexes with 16-electron and 18-electron configuration, J. Organomet. Chem., 397, 21-28.
2.) Prosenc M. H., Janiak C. und Brintzinger H. H. (1992): Agostic assistance to olefin insertion in alkylzirconocene cations: A molecular orbital study by the extended Hückel method, Organometallics, 11, 4036-4041.
3.) Jäger M., Prosenc M. H., Sonntag C. und Fischer H. (1994): Formation of cyclopropanes from electrophilic transition-metal carbene complexes and alkenes: An EHMO study of the reaction mechanism, New J. Chem., 19, 911-919.
4.) Mansel S., Rief U., Prosenc M. H., Kirsten R. und Brintzinger H. H. (1996): Ansa- metallocene derivatives 32. Zirconocene complexes with a spirosilane bridge: Syntheses, crystal structures and properties as olefin polymerization catalysts, J. Organomet. Chem., 512, 225-236.
5.) Harder, S., Prosenc, M. H. und Rief, U. (1996): Syntheses and x-ray structures of anionic sodocene sandwiches, Organometallics, 15,118 – 122.
6.) Bühl M., Hopp G., Philipsborn W., Beck S., Prosenc M. H., Rief U. und Brintzinger H. H. (1996): Zirconium-91 chemical shifts and line widths as indicators of coordination geometry distortions in zirconocene complexes Organometallics, 15, 778-785.
7.) Beck S., Prosenc M. H., Brintzinger H. H., Goretzki R., Herfert N und Fink G. (1996): Binuclear zirconocene cations with m-CH3 bridges in homogeneous Ziegler-Natta catalyst systems, J. Mol. Cat. A-Chemical., 111, 67-79.
8.) Schneider M. J., Suhm J., Mülhaupt R., Prosenc M. H. und Brintzinger H. H. (1997): Influence of indenyl ligand substitution pattern on metallocene catalyzed ethen copolymerization with 1-octene, Macromolecules, 30, 3164-3168.
9.) Prosenc M. H. und Brintzinger H. H. (1997): Zr-Alkyl isomerizations in zirconocene-catalyzed olefin polymerization: A density functional study, Organometallics, 16, 3889-3894.
10.) Beck S., Prosenc M. H. und Brintzinger H. H. (1998): Displacement of weakly coordinating anions from zirconocene alkyl cations by trialkyl phosphines - a model for olefin coordination in homogeneous ziegler-natta catalysis, J. Mol. Cat. A-Chemical, 128, 41-52.
11.) Prosenc M. H., Schaper F. und Brintzinger H. H. (1999): Chain growth in zirconocene-catalyzed olefin polymerization – DFT studies on possible paths and the influence of a second olefin ligand, in Metalorganic catalysts for synthesis and polymerization, Kaminsky W., ed., Springer-Verlag, Berlin, 223-237.
12.) Brintzinger H. H., Prosenc M. H., Schaper F., Weeber A. und Wieser U. (1999): Alternative force-field models for ansa-zirconocene complexes - vibrational and structural studies on Me2Si-bridged and tert.-butyl-substituted representatives, J. Mol. Structure, 485/486, 409-419.
13.) Lieber S., Prosenc M. H. und Brintzinger H. H. (2000): Zirconocen allyl complexes – dynamics in solution, reactions with aluminum alkyls, B(C6F5)3-induced propene insertion and density functional calculations on possible formation and reaction modes, Organometallics, 19, 377-387.
14.) Brookhart, M., Grant, B. E., Lenges, C. P., Prosenc, M. H. und White, P. S. (2000): High Oxidation State Organometallic Cobalt Complexes: Synthesis and Characterization of Dihydridodisilyl Cobalt(V) Species, Angew. Chem., 112, 1742-1745.
15.) Prosenc, M. H. und Holtmann, J. (2003): Insertion of CO into a Metal-Hydride Bond: Importance of Oxygen-Metal Bond on Kinetics and Themodynamics in (C5H5)2Zr(H)Cl. Manuskript in Bearbeitung.
16.) Meyer-Friedrichsen, T., Mecker, Ch., Prosenc, M. H., Heck, J. (2003): Donor-Acceptor Interaction in Cationic Archetype Mono- and Dinuclear Sesquifulvalene Complexes [(h 5-C5H5)Ru{µ-(h 5-C5H4)(h 7-C7H6)}RuL']n+ (n = 1,2). Manuskript in Bearbeitung.
Publikationen (Kristallographischer Co-Autor und kleinere Beiträge)
17.) Harder S. und Prosenc M. H. (1994): The simplest metallocene sandwich - the lithocene anion, Angew. Chem. Int. Ed. Engl., 33, 1744-1746.
18.) Dorer B., Prosenc M. H., Rief U. und Brintzinger H. H. (1994): Ansa- metallocene derivatives 30. Syntheses and structures of titanocene, zirconocene and vanadocene complexes with 2 ethanediyl bridges, Organometallics, 13, 3868-3872.
19.) Luinstra G. A., Rief U. und Prosenc M. H. (1995): Synthesis and reactivity of Cp2ZrH(OSO2CF3), a soluble alternative for Schwartz’s reagent, and the solid-state structure of its dimer, [Cp2Zr(OSO2CF3)(mH)]2 · 0.5 THF, Organometallics, 14, 1551-1552.
20.) Brinkmann P. H. P., Prosenc M. H. und Luinstra G. A. (1995): A puckered titanacyclobutane fragment as the result of a C-C coupling between a fulvene and a 2-methylallyl ligand: Structure of (h5-C5Me5)[h5:h2-C5Me4CH2CMe(CH2)2]Ti, Organometallics, 14, 5481-5482.
21.) Harder S. und Prosenc M. H. (1996): The heaviest alkali metallocene: Structure of an anionic cesocene triple-decker, Angew. Chem. Int. Ed. Engl., 35, 97-99.
22.) Barsties E., Schaible S., Prosenc M. H., Rief U., Röll W., Weyand O., Dorer B. und Brintzinger H. H. (1996): Ansa- metallocene derivatives 33. 2-Dimethylamino-substituted bis-indenyl zirconiumdichloride complexes with and without a dimethylsilylbridge - Syntheses, structures and properties in propene polymerization catalysis, J. Organomet. Chem., 520, 63-68.
23.) Hüttenhofer M., Prosenc M. H., Rief U., Schaper F. und Brintzinger H. H. (1996): Substituted silastannatetrahydro-s-indacenes as cyclopentadienyl transfer agents in the synthesis of silanediyl-bridged zirconocene complexes, Organometallics, 15, 4816-4822.
24.) Dorer B., Prosenc M. H., Rief U. und Brintzinger H. H. (1997): Ansa-metallocene derivatives 34. Ansa vanadocene complexes - Syntheses, structures and ligand exchange reactions, Coll. of Czech. Chem. Commun., 62, 265-278.
25.) Schaper F., Rentzsch M., Prosenc M. H., Rief U., Schmidt K. und Brintzinger H. H. (1997): Ansa-metallocene derivatives 36. Dimethylsilyl-bridged permethyl chromocene carbonyl complexes - Syntheses, crystal structures and interconversion reactions, J. Organomet. Chem., 534, 67-79.
26.) Huttenloch M. E., Dorer B., Rief U., Prosenc M. H., Schmidt K. und Brintzinger H.H. (1997): Ansa- metallocene derivatives 39. Biphenyl-bridged metallocene complexes of titanium, zirconium and vanadium: Syntheses, crystal structures and enantioseparation, J. Organomet. Chem., 541, 219-232.
27.) Schneider N., Prosenc M. H. und Brintzinger H. H. (1997): Cyclopenta[l]phenantrene titanium trichloride derivatives: Synthesis, crystal structure and propetries as catalysts for styrene polymerization, J. Organomet. Chem., 546, 291-295.
28.) Damrau H. R. H., Geyer A., Prosenc M. H., Weeber A., Schaper F. und Brintzinger H. H. (1998): Ansa-metallocene derivatives - 41. Chiral ansa-magnesocene complexes-syntheses, crystal structures and structural dynamics in solution, J. Organomet. Chem. 553, 331-343.
29.) Meyer-Friedrichsen, T., Mecker, Ch., Prosenc, M. H., Heck, J. (2001): Donor-Acceptor Interaction in Cationic Archetype Mono- and Dinuclear Sesquifulvalene Complexes [(h 5-C5H5)Fe{µ-(h 5-C5H4)(h 7-C7H6)}M'L']n+ (n = 1,2), Eur. J. Inorg. Chem., 239-248
30.) Farrell, T. Manning, A. R., Mitchella, G.,Heck, J., Meyer-Friedrichsen, T.,Malessa, M. Wittenburg, C., Prosenc, M. H., Cunningham, D. und McArdlec, P. (2002): Synthesis and Properties of a Novel Series of Organometallic Merocyanines Combining the Potent Electron Donating [(CpFeCO)2(m-CO)(m-C=CH-)] Fragment with Tropylium Type Acceptors, Eur. J. Inorg. Chem., 1677-1686.
31.) Xiaofeng Zhang, Prosenc, M. H., Meyer-Friedrichsen, T. und Heck, J. (2003): [(h 6-Cyclooctatetraene) (h 5-(+)-neomenthylcyclopentadienyl)ruthenium(II)] Hexafluorophosphate, Synthesis and Characterization of a Chiral Mixed Sandwich Complex, Eur. J. Inorg. Chem., 313-317.
32.) Meyer-Friedrichsen, T., Wong, H., Prosenc, M. H. und Heck, J. (2003): Vinylogue Mono- and Bimetallic Sesquifulvalene and Monohydro Sesquifulvalene Complexes for Second Harmonic Generation, Eur. J. Inorg. Chem., im Druck.
Tagungsbeiträge:
1.) Prosenc, M. H. and Brintzinger, H. H. (1993): Flexibility of ansa-zirconocenes: Forcefields for molecular mechanics studies, 40 Years of Ziegler Catalysis Symposium, Freiburg 1993
2.) Prosenc, M. H. and Brintzinger, H. H. (1993): Flexibility of ansa-zirconocene complexes, International PhD Student Symposium at Prag
3.) Mansel, S., Prosenc, M. H., Reinmuth, A. and Brintzinger,H. H. (1994): Spirosilane bridged zirconocene complexes, Stepol Conference, Mailand 1994
4.) Beck, S., Prosenc, M. H., Geyer, A., Brintzinger,H. H., Goretzky, R., Fink, G. (1995): Gleichgewichtsreaktionen in Metallocen-Katalysatorsystemen: NMR Untersuchungen und Polymerisationskinetik, Dechema-Tagung 1995
5.) Prosenc, M. H. and Brintzinger, H. H. (1995): Models of zirconocene catalysts, International PhD Student Symposium at Heiligenstadt 1995
6.) Luinstra G.A., Prosenc M.H., Rief U. and Huisgen, N. S.(1995): Advanteges of weakly coordinating anions in group-4 transition-metal chemistry. Abstr. Pap. Am. Chem. Soc. 209: 2-INOR Part 1 APR 2 1995
7.) Prosenc, M. H. and Brintzinger, H. H. (1997): Influence of additional olefin to chain propagation, Symposium Mechanisms in Metallocene Catalyzed Olefin Polymerization at Konstanz, April 1997
8.) Prosenc, M. H. and Brintzinger, H. H. (1997): Force fields for ansa-zirconocene complexes, Modelling Workshop at Konstanz, Juni 1997
9.) Prosenc, M. H. and Brintzinger, H. H. (1997): Influence of Monomer Concentration in Zirconocene Catalyzed Olefin Polymerization, OMCOS 9 - Symposium on Organometallic Chemistry Directed towards Organic Synthesis, Göttingen 1997
10.) Lieber, S., Prosenc, M. H. and Brintzinger H. H. (1998): Allyl Complexes as Deactivation Products of Zirconocene based Polymerisation Catalysts, ISHC 11 in St. Andrews, Schottland 1998
11.) Lieber, S., Prosenc, M. H. and Brintzinger, H. H. (1998): Alkyl- and Allyl transfer in Zirconocene-based Polymerization catalyst systems. International Symposium on Metalorganic Catalysts for Syntheses and Polymerization, Hamburg 1998
12.) Brintzinger H. H., Leclerc, M. K., Prosenc, M. H., Schaper, F. (1999): Stereocontrol and chain-growth mechanisms in polymerizations of alpha-olefins with chiral ansa-zirconocene catalysts, Abstr. Pap. Am. Chem. Soc., 217: 328A-INOR, Part 1, 1999.
13.) Prosenc, M. H. and Brookhart, M. S. (1999): Mechanistic Investigations in Homogeneous Late Metal Catalyzed Hydroacylations: A Density Functional Study, 113th Local Meeting of the American Chemical Society, Chapel Hill, April 1999.
14.) Prosenc, M. H. and Brookhart, M. S. (1999): Mechanistic Investigations in Homogeneous Late Metal Catalyzed Olefin Polymerization, User Forum of the North Carolina Supercomputing Center, Research Triangle Park May 1999.
15.) Reinartz S., Prosenc, M. H. , White, P. S., Brookhart, M. and Tempelton, J. L. (1999): C-H Bond Activation and Formation by Tris(pyrazolyl)borate Platinum Complexes, Abstr. Pap. 37th IUPAC Congress / 27th GDCh General Meeting, 1069, INO-2-071, August 14 - 19, 1999, in Berlin.
16.) Wieser, U., Prosenc, M. H. and Brintzinger H. H. Abstr. Pap. 37th IUPAC Congress/ 27th General Meeting of the GDCh, 1081, INO-2-083, Aug. 14.-19. 1999 in Berlin.
17.) Reinartz, S., Prosenc, M. H., Brookhart, M. and Tempelton, J. L. (1999): C-H Bond Activation and Formation by Tris(pyrazolyl)borate and Tris(pyrazolyl)borateH+ Platinum Complexes, Abstr. Pap. Am. Chem. Soc., 218: 194-INOR, Part 1, Aug. 1999.
18.) Prosenc, M. H., Meyer-Friedrichsen, T. and Heck, J. (2001): Nonlinear Optical Properties of Dinuclear Organometallic Complexes: Influence of Bridging Bond Length on First Hyperpolarizability, NCCC- Conference in Nordwijkerhout, NL, Book of Abstr. Pap.: 204, K-1, Mar. 2001.
19.) Prosenc, M. H. (2002): Transition Metal-Catalyzed Formation of Methanol: DFT-Calculations on Formation of a Formyl Ligand, ISHC-13 in Tarragona, ESP, Poster Nr. 343, Sep. 2002.
20.) Böhme, A. and Prosenc, M. H. (2002): Synthesis of Binuclear Macrocyclic Complexes of the Robson-Type Supported by Molecular Modelling, Dechema Workshop on Molecular Modelling, Frankfurt (Main), Poster Nr. 5, Dez. 2002.
Vorträge (Auswahl)
1.) Prosenc, M. H. und Brintzinger H. H., Einfluß einer a-agostischen Wasserstoff-Bindung auf die Olefinpolymerisation, BASF AG, Ludwigshafen, Juni 1991.
2.) Prosenc, M. H. und Brintzinger H. H., Berechnung von Kraftkonstanten zur Entwicklung von Kraftfeldern von Zirkonocenkatalysatoren, BASF AG, Ludwigshafen, April 1993.
3.) Prosenc, M. H. und Brintzinger H. H., Kraftfeldmodelle von Zirkonocenkatalysatoren, Universität Zürich, August 1993.
4.) Prosenc, M. H. und Brintzinger H. H., Calculations on Zr-Alkyl Isomerizations, OPTMO-Meeting in Mailand, März 1997.
5.) Prosenc, M. H. und Brintzinger H. H., Chain Growth, Chain Termination and Chain Isomerization in Zirconocene-Catalyzed Olefin Polymerization - DFT Studies on Possible Reaction Paths and the Influence of a Second Olefin Ligand, Union Carbide, Bount Brook, NJ (USA), Oktober 1998.
6.) Prosenc, M. H. und Heck, J., Calculation of NLO Properties in Bridged Dinuclear Organotransition-Metal Complexes. Influence of Bridging p-Bond Length on first Hyperpolarizability: A DFT Study, COST-D14 Meeting in Paris, University IV Paris, April 2001.
7.) Prosenc, M. H., Mechanistic Investigations in Metal-Catalyzed Hydrogenation of CO, Dept. de Química Fisica i Inorgánica, Rovira i Virgili University, Tarragona (ES), Dezember 2001.
8.) Prosenc, M. H. Investigations on Metal-Catalyzed Hydrogenation of CO, Institut für Anorganische Chemie der Universität Zürich, Zürich (CH), Juni 2002.
9.) Prosenc, M. H. und Brintzinger H. H., Calculations on Zirconocene Catalysis, SABIC (DSM), Geleen (NL), December 2002.
Patent
1.) Wünsch, J., Brintzinger, H. H., Schneider, N. und Prosenc, M. H. (1998): Cyclopenta[l]phenantrene Metal Complex Systems. WO9857995A2.